I have seen, inspected, and repaired several failed SMC units, that the owners tried to "protect" by stuffing grease under the boot, only to have it collect all kinds of crap jamming things up.
From the factory, the pre-assembled SMC units, have a very small amount of silicone grease between the ball end of the push rod, and the seat of the piston. This is to make sure these two parts have smooth movement between them.
By adding more grease to this area, you are simply risking road grime getting into this area, and the brake dust turning into lapping compound etc.
Dirt and stuff sticks to grease making things worse, not better.
Too much grease also can work itself down into the SMC unit itself and contaminate the brake fluid etc.
I've seen folks spray WD40 in this area, thinking they are doing a good thing, only to find they destroyed the SMC in very short time.
The same thing goes for the brake pad retaining pin, if you want to prevent the pads from moving correctly, coat these with a lot of grease, and watch the crap start to gather, preventing smooth movement.
Clean/Dry is often better, or a very small amount of Antiseaze in two very small strips just where the contact points are, will keep this area clean and working correctly.